What PDF is
PDF describes a page: glyphs at coordinates, not rows and columns. A table in a PDF is a visual arrangement, not a data structure.
Reports, invoices, statements and anything sent to be read rather than processed.
What INI is
INI is the oldest configuration format still in daily use: named sections, then key equals value lines.
Windows software, PHP, Git and a long tail of tools that never moved on.
What changes when you convert PDF to INI
Every character in a text-based PDF carries its position on the page. Characters sharing a baseline are one row. Columns are found from the vertical strips no character ever occupies, which is why extraction works cleanly on a document laid out with spacing and badly on one laid out with ruled lines. A header repeated at the top of each page is detected and dropped rather than landing in the middle of the data.
Each row becomes a section named after its first column, with one key per remaining column.
What carries over from PDF to INI
PDF records 2 things about a table that INI has no way to hold.
A line break inside a cell ends the row in INI, so line breaks are replaced rather than carried through.
Anything visual in the PDF - weight, alignment, colour, column widths - has no counterpart in INI and is dropped. The values are what survives.
This is the direction that recovers structure: PDF has no table in it to read, only an arrangement that looks like one, so the rows and columns are inferred rather than read.