TSV is CSV with tabs instead of commas. Because tabs almost never appear inside a value, quoting is rarely needed and the files are easier to read by eye.
Who uses it
Bioinformatics, log processing, and anyone who has copied a block of cells out of a spreadsheet: the clipboard format is TSV.
Reading TSV
The tab is unambiguous, so there is no delimiter to guess. This is the most reliable of the delimited formats to read.
Writing TSV
Pick TSV over CSV when your values contain commas. Pasting the result straight into a spreadsheet fills the cells correctly with no import dialog.